Skip to main content
SpringerLink
Log in

Change in the selectivity of the action of catalysts during the hydrogenation of the dienone group

Communication 6. Influence of modification on a Ni-Al2O3 catalyst with cations of cadmium, zinc, and silver

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The modifying action of cadmium (and zinc) cations on a Ni-Al2O3 catalyst with respect to the direction of addition of hydrogen to crotonylidenacetone is similar to the action of metallic cadmium.

  2. 2.

    The modifying action of cadmium and zinc ions is specific. In contrast to these cations, treatment of a nickel catalyst with silver acetate has no influence on the direction of the addition of hydrogen to the dienone.

  3. 3.

    Under conditions of hydrogenation in the presence of a Ni-Al2O3 catalyst, the cadmium cation is not reduced to the metal.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. L. Kh. Freidlin, N. V. Borunova, and L. I. Gvinter, Dokl. Akad. Nauk SSSR,163 1179 (1965); N. V. Borunova, L. Kh. Freidlin, and T. Atabekov, Izv. Akad. Nauk SSSR, Ser. Khim., 1060 (1968).

    Google Scholar 

  2. L. Kh. Freidlin, L. I. Gvinter, N. V. Borunova, S. F. Dymova, and I. M. Kustanovich, this issue, p. 1008.

  3. G. D. Zakumbaeva, S. A. Musina, and D. V. Sokol'skii, Tr. In-ta Khim. Nauk AN KazSSR,14, 215 (1966); G. D. Zakumbaeva, Tr. In-ta Khim. Nauk AN KazSSR,8, 73 (1962).

    Google Scholar 

  4. L. Kh. Freidlin, N. V. Borunova, G. I. Samokhvalov, M. A. Miropol'skaya, M. Ts. Yanotovskii, L. I. Gvinter, and N. I. Fedotova, Izv. Akad. Nauk SSSR, Ser. Khim., 996 (1964).

  5. V. S. Markevich, M. L. Gerchuk, and S. M. Markevich, Neftekhimiya,6, 286 (1966).

    Google Scholar 

  6. A. N. Frumkin, G. N. Mansurov, V. E. Kazarinov, and N. A. Balashova, Collection,31, 806 (1966); G. A. Zakumbaeva, Dissertation [in Russian], Alma-Ata (1970).

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    N. V. Borunova, A. A. Slinkin, L. Kh. Freidlin & T. Atabekov

Authors
  1. N. V. Borunova
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Slinkin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. L. Kh. Freidlin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. T. Atabekov
    View author publications

    You can also search for this author in PubMed Google Scholar

Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1056–1059, May, 1972.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Borunova, N.V., Slinkin, A.A., Freidlin, L.K. et al. Change in the selectivity of the action of catalysts during the hydrogenation of the dienone group. Russ Chem Bull 21, 1012–1015 (1972). https://doi.org/10.1007/BF00853758

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00853758

Keywords

Search

Navigation