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Mechanism of the oxidation of higher olefins with a straight carbon chain

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The basic products of the oxidation of 1-nonene are nonene oxide and organic acids: caprylic, enanthic, caproic, acetic, and formic. There are practically no products containing a double bond in the reaction mixture.

  2. 2.

    The main epoxidizing agents in the oxidation of 1-nonene are acyl peroxide radicals, formed during the reaction in the oxidation of the corresponding aldehydes.

  3. 3.

    The reaction rate and length of the chain of oxidation of 1-nonene are substantially greater than the corresponding values for paraffin hydrocarbons, which is evidently due to the participation of aldehydes in the oxidation of 1-nonene.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    L. G. Privalova, L. D. Tyutchenkova, S. P. Kirichenko & Z. K. Maizus

Authors
  1. L. G. Privalova
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  2. L. D. Tyutchenkova
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  3. S. P. Kirichenko
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  4. Z. K. Maizus
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 1042–1048, May, 1972.

The authors would like to thank Yu. V. Kisin for his aid in the measurements performed by the method of IR spectroscopy.

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Privalova, L.G., Tyutchenkova, L.D., Kirichenko, S.P. et al. Mechanism of the oxidation of higher olefins with a straight carbon chain. Russ Chem Bull 21, 998–1003 (1972). https://doi.org/10.1007/BF00853755

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  • DOI: https://doi.org/10.1007/BF00853755

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