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Synthesis and isomerization of 2,2-dialkyl-5-propyltetrahydrofurans

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    2,2-Dialkyl-5-propyltetrahydrofurans are formed in 70% yield in the hydrogenation of 1-furyl-3-alkylalkanols-3 according to a continuous flow method on Pt-C at 220° and atmospheric pressure.

  2. 2.

    On the same catalyst, but at 280°, 2,2-dialkyl-5-propyltetrahydrofurans are isomerized to the corresponding aliphatic ketones in 90% yield.

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Literature cited

  1. N. I. Shuikin and I. F. Bel'skii, Dokl. AN SSSR,137, 622 (1961).

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    I. F. Bel'skii, N. I. Shuikin & Z. K. Vol'nova

Authors
  1. I. F. Bel'skii
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  2. N. I. Shuikin
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  3. Z. K. Vol'nova
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Bel'skii, I.F., Shuikin, N.I. & Vol'nova, Z.K. Synthesis and isomerization of 2,2-dialkyl-5-propyltetrahydrofurans. Russ Chem Bull 13, 342–343 (1964). https://doi.org/10.1007/BF00853701

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  • DOI: https://doi.org/10.1007/BF00853701

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