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Hydroborating of dienes with chloroborane

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Dienes (diallyl, pentadiene-1,4, butadiene-1,3) are hydroborated by chloroborane in ether solution at room temperature, the orientation of the addition being determined by the nature of the diene.

  2. 2.

    The reaction of chloroborane with diallyl can be used to produce 1-chloroboracycloheptane.

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Literature cited

  1. H. Nöth and H. Beyer, Chem. Ber.,93, 2251 (1960).

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  4. B. M. Mikhailov and T. A. Shchegoleva, Izv. AN SSSR. Otd. khim. n.,1961, 1142.

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    T. A. Shchegoleva, E. M. Shashkova, V. G. Kiselev & B. M. Mikhailov

Authors
  1. T. A. Shchegoleva
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  2. E. M. Shashkova
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  3. V. G. Kiselev
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  4. B. M. Mikhailov
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Shchegoleva, T.A., Shashkova, E.M., Kiselev, V.G. et al. Hydroborating of dienes with chloroborane. Russ Chem Bull 13, 336–338 (1964). https://doi.org/10.1007/BF00853699

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  • DOI: https://doi.org/10.1007/BF00853699

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