Conclusions
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1.
The conditions of stereospecific polymerization of simple vinyl ethers at room temperature under the influence of a catalyst produced from VOCl3, LiC3H7, and Al(i-C4H39)3 were found.
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2.
This system proved especially effective for the polymerization of vinyl n-butyl ether, from which polymers were obtained with molecular weights up to 1.46·106.
Literature cited
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A. V. Bogdanova, M. F. Shostakovskii, and S. Shamakhmudova, Izv. AN SSSR, Ser. khim. (in press).
E. J. Vandenberg, R. F. Heck, and D. S. Breslow, J. Polymer Sci., 41, 519 (1959); German Patent 1033413 (1958).
G. Natta, G. Dell-Asta, G. Mazzanti, U. Giannini, and S. Cesca, Angew. Chem., 71, 207 (1959).
A. V. Bogdanova, Zh. Vysokomolekul. Soedinenii, 2, 576 (1960).
M. F. Shostakovskii, Simple Vinyl Ethers [in Russian], Moscow (1952), p, 31.
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Shostakovskii, M.F., Bogdanova, A.V. & Shamakhmudova, S. High-molecular polymers of vinyl n-butyl ether. Russ Chem Bull 13, 334–335 (1964). https://doi.org/10.1007/BF00853698
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DOI: https://doi.org/10.1007/BF00853698