Reaction of vinyl ethers and vinyl sulfides with triethyl trithioorthoformate

  • A. N. Dolgikh
  • A. V. Bogdanova
  • M. F. Shostakovskii
Organic and Biological Chemistry
  • 19 Downloads

Summary

  1. 1.

    A study was made of the reaction of vinyl ethers and vinyl sulfides with triethyl trithioorthoformate in presence of BF3 etherate; it leads to the formation of dimercaptals and mercaptal acetals of malonaldehyde.

     
  2. 2.

    A method is proposed for the synthesis of malonaldehyde bis[diethyl mercaptal] from ethyl vinyl sulfide or a vinyl ether and triethyl trithioorthoformate in presence of BF3 etherate.

     

Keywords

Acetal Ether Ethyl Sulfide Vinyl 

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Copyright information

© Consultants Bureau Enterprises, Inc. 1965

Authors and Affiliations

  • A. N. Dolgikh
    • 1
  • A. V. Bogdanova
    • 1
  • M. F. Shostakovskii
    • 1
  1. 1.N. D. Zelinskii Institute of Organic ChemistryAcademy of SciencesUSSR

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