Skip to main content
SpringerLink
Log in

Kinetics of the dehydrogenati on and dehydration of isopropanol and the dehydrogenation of tetralin on samarium oxide

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The true activation energies of the dehydrogenation and dehydration of isopropanol and the dehydrogenation of tetralin and the bond energies of C, H, and O with Sm2O3 were determined.

  2. 2.

    The relative adsorption coefficients of the reaction products of isoprepanol and tetralin depend on the temperature.

  3. 3.

    The heats of adsorption of the reaction products of isopropanol (hydrogen, acetone, water, and propylene) are greater than the heats of adsorption of the alcohol.

  4. 4.

    The heat of adsorption of tetralin is greater than the heats of adsorption of its reaction products, hydrogen and naphthalene.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

Literature cited

  1. A. A. Tolstopyatova and A. A. Balandin, Dokl. AN SSSR, 138, 1365 (1961).

    Google Scholar 

  2. A. A. Tolstopyatova, Yü Chi'i-ch'üan, and L. S. Gorshkova, Izv. AN SSSR, Otd. Khim. N., 8 (1964).

  3. A. A. Balandin, A. A. Tolstopyatova, and P'in Pi-Hsiang, Izv. AN SSSR, Otd. Khim. N., 974 (1963).

  4. A. A. Tolstopyatova, A. A. Balandin, and P'in Pi-Hsiang, Izv. AN SSSR, Otd. Khim. N., 1154 (1963).

Download references

Author information

Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    A. A. Balandin, A. A. Tolstopyatova & Yü Ch'i-ch'üan

Authors
  1. A. A. Balandin
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. A. Tolstopyatova
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yü Ch'i-ch'üan
    View author publications

    You can also search for this author in PubMed Google Scholar

Rights and permissions

Reprints and permissions

About this article

Cite this article

Balandin, A.A., Tolstopyatova, A.A. & Ch'i-ch'üan, Y. Kinetics of the dehydrogenati on and dehydration of isopropanol and the dehydrogenation of tetralin on samarium oxide. Russ Chem Bull 13, 241–245 (1964). https://doi.org/10.1007/BF00853678

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/BF00853678

Keywords

Search

Navigation