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Polymorphism of molecules and complex ions in oxygen compounds of silicon and phosphorus. Report 1. Nature of the Si-O-Si bonds and values of the valence angles of oxygen

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Changes in the order of the bonds R3'Si-OR as a function of the nature of the substituents R and R′ have been discussed on the basis of the literature data and original data.

  2. 2.

    The high sensitivity of the valence angle of the “bridge” oxygen atom in X-O-X bonds (X=Si, P) to variation of the nature of these bonds, primarily determined by the participation of dπ-pπ bonds, has been demonstrated.

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Authors and Affiliations

  1. I. V. Grebenshchikov Institute of Silicate Chemistry, Academy of Sciences, USSR

    A. N. Lazarev

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  1. A. N. Lazarev
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Lazarev, A.N. Polymorphism of molecules and complex ions in oxygen compounds of silicon and phosphorus. Report 1. Nature of the Si-O-Si bonds and values of the valence angles of oxygen. Russ Chem Bull 13, 218–223 (1964). https://doi.org/10.1007/BF00853674

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  • DOI: https://doi.org/10.1007/BF00853674

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