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Behavior of trisacetylaminomethane in trifluoroacetic acid

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the behavior of trisacetylaminomethane in trifluoroacetic acid.

  2. 2.

    All of the trisacetylaminomethane is rapidly and completely hydrolyzed to a mixture of acetamide and formylacetamide when an equimolar amount of water is present in the acid. Under the conditions where the amount of water present is insufficient for complete hydrolysis, or if it is absent, the corresponding amount of trisacetylaminomethane remains in solution.

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Literature cited

  1. S. S. Novikov, L. I. Khmel'nitskii, S. N. Shvedova, E. V. Shepelev, and O. V. Lebedev, Izv. Akad. Nauk SSSR, Ser. Khim., 888 (1971).

  2. G. Binsch, J. B. Lambert, B. W. Roberts, and J. D. Roberts, J. Amer. Chem. Soc.,86, 5564 (1964); A. K. Bose and J. Kugajevsky, Tetrahedron,23, 1489 (1967).

    Google Scholar 

  3. N. V. Smirnova, A. P. Skoldinov, and K. A. Kocheshkov, USSR Patent No. 77804 (1948).

  4. W. Armarego and T. Kobayashi, Org. Magn. Res.,2, 123 (1970).

    Google Scholar 

  5. Yu. K. Yur'ev, Practical Guide in Organic Chemistry [in Russian], Vol. 2, MGU (1957), p. 215.

  6. H. Bredereck, F. Effenberger, and H. J. Treiber, Ber.,96, 1505 (1963).

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    G. A. Kalabin, S. N. Shvedova, E. V. Shepelev, O. V. Lebedev, L. I. Khmel'nitskii & S. S. Novikov

Authors
  1. G. A. Kalabin
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  2. S. N. Shvedova
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  3. E. V. Shepelev
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  4. O. V. Lebedev
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  5. L. I. Khmel'nitskii
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  6. S. S. Novikov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 12, pp. 2809–2812, December, 1971.

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Kalabin, G.A., Shvedova, S.N., Shepelev, E.V. et al. Behavior of trisacetylaminomethane in trifluoroacetic acid. Russ Chem Bull 20, 2670–2673 (1971). https://doi.org/10.1007/BF00853651

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  • DOI: https://doi.org/10.1007/BF00853651

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