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Synthesis of bis-(2-fluoro-2, 2-dinitroethyl) nitramine and tris-(2-fluoro-2,2-dinitroethyl) amine

  • R. G. Gafurov
  • S. I. Sviridov
  • F. Ya. Natsibullin
  • L. T. Eremenko
Organic and Biological Chemistry

Conclusions

  1. 1.

    By means of a fluorination of salts of bis-(2,2-dinitroethyl)nitramine and tris-(2,2-dinitroethyl)-amine in aqueous solutions by elementary fluorine, we obtained for the first time bis-2-fluoro-2,2-dinitro-ethyl) nitramine and tris-(2-fluoro-2,2-dinitroethyl)amine.

     
  2. 2.

    We made a counter-synthesis of bis-(2-fluoro-2,2-dinitroethyl)nitramine through condensation of 2-fluoro-2,2-dinitroethanol with ammonia and nitration of the Mannich base obtained.

     

Keywords

Ammonia Aqueous Solution Fluorine Nitration Nitramine 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

  1. 1.
    L. T. Eremenko, R. G. Gafurov, and S. I. Sviridov, Zh. Organ. Khim.,5, 31 (1969).Google Scholar
  2. 2.
    L. T. Eremenko, F. Ya. Natsibullin, I. P. Borovinskaya, and N. D. Karpova, Izv. Akad. Nauk SSSR, Ser. Khim., 431 (1968).Google Scholar
  3. 3.
    L. T. Eremenko and F. Ya. Natsibullin, Izv. Akad. Nauk SSSR, Ser. Khim., 676 (1968).Google Scholar
  4. 4.
    L. T. Eremenko and F. Ya. Natsibullin, Izv. Akad. Nauk SSSR, Ser. Khim., 1331 (1969).Google Scholar
  5. 5.
    K. Klager, J. Organ. Chem.,23, 1519 (1958).Google Scholar
  6. 6.
    V. I. Slovetskii, L. V. Okhlobystina, A. A. Fainzilberg, A. I. Ivanov, L. I. Birinkova, and S. S. Novikov, Izv. Akad. Nauk SSSR, Ser. Khim., 431 (1965).Google Scholar
  7. 7.
    H. G. Adolph and M. J. Kamlet, J. Amer. Chem. Soc.,88, 4761 (1966).Google Scholar
  8. 8.
    H. G. Adolph and M. J. Kamlet, J. Organ. Chem.,34, 45 (1969).Google Scholar

Copyright information

© Consultants Bureau 1970

Authors and Affiliations

  • R. G. Gafurov
    • 1
  • S. I. Sviridov
    • 1
  • F. Ya. Natsibullin
    • 1
  • L. T. Eremenko
    • 1
  1. 1.Institute of Chemical PhysicsAcademy of Sciences of the USSRUSSR

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