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Catalytic copolymerization of ethylene with acrylonitrile

  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Complexes of VCl4, VOCl3,TiCl4, and AlCl3 with acrylonitrile (AN) were produced, their properties were studied, and it was shown that the coordination of AN with the central atom is accomplished through the unshared pair of electrons of the nitrogen atom.

  2. 2.

    Acrylonitrile stabilizes catalytic systems based on VCl4 but sharply reduces their activity in the polymerization of ethylene.

  3. 3.

    The introduction of AlCl3 into catalytic systems based on acrylonitrile complexes of VCl4 and diisobutyl aluminum chloride promotes an increase in their activity in the polymerization of ethylene. The indicated effect is evidently due to a recoordination of AN from VCl4 to AlCl3.

  4. 4.

    Acrylonitrile is brought into polymerization and forms copolymers with ethylene.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    P. E. Matkovskii, I. D. Leonov, G. A. Beikhol'd, A. D. Pornogai1o, Yu. V. Kissin & N. M. Chirkov

  2. Institute of the Chemistry of Petroleum and Natural Salts, Academy of Sciences of the Kazakh SSR, USSR

    P. E. Matkovskii, I. D. Leonov, G. A. Beikhol'd, A. D. Pornogai1o, Yu. V. Kissin & N. M. Chirkov

Authors
  1. P. E. Matkovskii
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  2. I. D. Leonov
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  3. G. A. Beikhol'd
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  4. A. D. Pornogai1o
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  5. Yu. V. Kissin
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  6. N. M. Chirkov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 6, pp. 1311–1318, June, 1970.

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Matkovskii, P.E., Leonov, I.D., Beikhol'd, G.A. et al. Catalytic copolymerization of ethylene with acrylonitrile. Russ Chem Bull 19, 1240–1246 (1970). https://doi.org/10.1007/BF00852666

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  • DOI: https://doi.org/10.1007/BF00852666

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