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Hydrolysis of dimethyl 1-acetoxy-2,2,2-trichloroethyl phosphonate

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

The hydrolysis of chloroacetophos in water includes the parallel cleavage of acetic acid, hydrochloric acid and methanol. The ratio of the products, formed in the parallel steps, was determined, and we also determined the total rate constant for the hydrolysis of chloroacetophos.

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Literature cited

  1. K. V. Nikonorov and V. A. Nikonenko, Izv. Akad. Nauk SSSR, Otd. Khim. Nauk, 1882 (1962).

  2. Z. Sh. Minyusheva, I. D. Neklesova, and M. A. Kudrina, Chemistry and Application of Organophosphorus Compounds [in Russian], Izd. AN SSSR (1962), p. 539.

  3. G. Schrader, New Organophosphorus Insecticides [Russian translation], Mir (1965), p. 41.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    L. S. Andreeva, A. A. Andrianov, V. E. Bel'skii, M. F. Vavilova, É. A. Gurylev & K. V. Nikonorov

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  1. L. S. Andreeva
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  2. A. A. Andrianov
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  3. V. E. Bel'skii
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  4. M. F. Vavilova
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  5. É. A. Gurylev
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  6. K. V. Nikonorov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2336–2338, October, 1971.

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Andreeva, L.S., Andrianov, A.A., Bel'skii, V.E. et al. Hydrolysis of dimethyl 1-acetoxy-2,2,2-trichloroethyl phosphonate. Russ Chem Bull 20, 2219–2221 (1971). https://doi.org/10.1007/BF00851293

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  • DOI: https://doi.org/10.1007/BF00851293

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