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Study of the catalytic action of polyazopolyarenes containing dialkyl(aralkyl)amino groups in the liquid-phase oxidation of cumene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The catalytic action of polyazopolyarenes is importantly dependent on the presence and the amounts of azoxy groups in them.

  2. 2.

    Polyazopolyarenes apparently cause an accelerated decomposition of cumene hydroperoxide (either present in the starting cumene, or formed during the reaction process), as a result of which the number of radicals, initiating oxidation, is sharply increased.

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Literature cited

  1. M. P. Terpugova, V. G. Mazur, and I. L. Kotlyarevskii, Izv. Akad. Nauk SSSR, Ser. Khim., 2097 (1971).

  2. V. G. Mazur, M. P. Terpugova, and I. L. Kotlyarevskii, Vysokomolekul. Soedin. (in press).

  3. A. I. Min'kov, G. M. Alikina, Yu. M. Gridnev, and N. P. Keier, Kinetika i Kataliz,7, 632 (1966).

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion, Siberian Branch of the Academy of Sciences of the USSR, USSR

    V. G. Mazur, M. P. Terpugova & I. L. Kotlyarevskii

Authors
  1. V. G. Mazur
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  2. M. P. Terpugova
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  3. I. L. Kotlyarevskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2305–2307, October, 1971.

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Mazur, V.G., Terpugova, M.P. & Kotlyarevskii, I.L. Study of the catalytic action of polyazopolyarenes containing dialkyl(aralkyl)amino groups in the liquid-phase oxidation of cumene. Russ Chem Bull 20, 2179–2181 (1971). https://doi.org/10.1007/BF00851278

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  • DOI: https://doi.org/10.1007/BF00851278

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