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Organometallic compounds containing a Fe-Ge bond

Communication 3. Action of grignard reagents on π-C5H5(CO)2FeGeCl3

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Alkylation at the germanium atom, without rupture of the Fe-Ge bond, occurs when CH3MgI or C2H5MgBr is reacted withπ-C5H5(CO)2FeGeCl3.

  2. 2.

    Together with the alkylation products, the formation of germanes of general formula [π-C5H5(CO)2·Fe-GeR2]2 was detected, the yield of which depends on the reaction temperature.

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Literature cited

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    A. N. Nesmeyanov, K. N. Anisimov, N. E. Kolobova & F. S. Denisov

Authors
  1. A. N. Nesmeyanov
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  2. K. N. Anisimov
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  3. N. E. Kolobova
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  4. F. S. Denisov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2287–2290, October, 1971.

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Nesmeyanov, A.N., Anisimov, K.N., Kolobova, N.E. et al. Organometallic compounds containing a Fe-Ge bond. Russ Chem Bull 20, 2158–2160 (1971). https://doi.org/10.1007/BF00851271

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  • DOI: https://doi.org/10.1007/BF00851271

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