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α-Bromo-β-(trichloromethyl)styrene and some of its transformations

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The adduct of phenylacetylene and trichlorobromomethane, namelyα-bromo-β-(trichloromethyl)styrene, was obtained by free-radical addition.

  2. 2.

    The dehydrohalogenation ofα-bromo-β-(trichloromethyl)styrene in alcoholic alkali solution leads to the formation ofβ,β-dichlorovinyl phenyl ketone, and to the formation of trichloromethylphenylacetylene in triethylamine medium.

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Literature cited

  1. M. S. Kharasch, J. J. Jerome, and W. H. Urry, J. Org. Chem.,15, 966 (1950).

    Google Scholar 

  2. E. J. Heiba and R. M. Dessau, J. Am. Chem. Soc.,89, 3772 (1967).

    Google Scholar 

  3. D. C. Bishop, S. C. R. Meacock, and R. N. Williamson, J. Chem. Soc., C, 670 (1966).

    Google Scholar 

  4. P. P. Kisilitsa, M. I. Cherkashin, and A. A. Berlin, Izv. Akad. Nauk SSSR, Ser. Khim., 2453 (1967).

  5. S. Searles, Jr., R. A. Sanchez, R. L. Soulen, and D. G. Kundiger, J. Org. Chem.,32, 2655 (1967).

    Google Scholar 

  6. A. N. Nesmeyanov, R. Kh. Freidlina, L. I. Zakharkin, and A. B. Belyavskii, Zh. Obshch. Khim.,26, 1070 (1956).

    Google Scholar 

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    R. G. Sultangareev, Yu. G. Kryazhev & L. I. Vasilenko

Authors
  1. R. G. Sultangareev
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  2. Yu. G. Kryazhev
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  3. L. I. Vasilenko
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2284–2287, October, 1971.

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Sultangareev, R.G., Kryazhev, Y.G. & Vasilenko, L.I. α-Bromo-β-(trichloromethyl)styrene and some of its transformations. Russ Chem Bull 20, 2155–2157 (1971). https://doi.org/10.1007/BF00851270

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  • DOI: https://doi.org/10.1007/BF00851270

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