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Stability of O-glycoside linkages of O-maltoside and O-melibioside derivatives of serine in acid and alkaline media

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the comparative stability of the O-glycoside carbohydrate-amino acid and carbohydrate-carbohydrate linkages of the O-maltoside and O-melibioside of some serine derivatives in both acid and alkaline media.

  2. 2.

    The O-glycoside carbohydrate-carbohydrate linkage is more labile in acid medium. In alkaline medium the O-glycoside carbohydrate-amino acid linkage is cleaved by theβ-elimination mechanism, while the stability of the O-glycoside carbohydrate-carbohydrate linkages is close to the stability of the same linkages in the corresponding disaccharides.

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Literature cited

  1. V. A. Derewitskaya, M. G. Vafina, and N. K. Kochetkov, Carbohydrate Res.,3, 377 (1967).

    Google Scholar 

  2. N. K. Kochetkov, V. A. Derevitskaya, L. M. Likhosherstov, V. M. Kalinevich, and O. S. Novikova, Izv. Akad. Nauk SSSR, Ser. Khim., 2509 (1969).

  3. N. K. Kochetkov, V. A. Derevitskaya, L. M. Likhosherstov, M. D. Martynova, and S. N. Senchenkova, Carbohydrate Res.,12, 437 (1970).

    Google Scholar 

  4. T. Nash, Biochem. J.,55, 416 (1953).

    PubMed  Google Scholar 

  5. S. A. Barker, A. R. Law, P. J. Somers, and M. Stacey, Carbohydrate Res.,3, 435 (1967).

    Google Scholar 

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences of the USSR, USSR

    V. A. Derevitskaya, L. M. Likhosherstov, O. S. Novikova & N. K. Kochetkov

Authors
  1. V. A. Derevitskaya
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  2. L. M. Likhosherstov
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  3. O. S. Novikova
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  4. N. K. Kochetkov
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Additional information

Translated from Izvestiya Akademiya Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2246–2253, October, 1971.

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Derevitskaya, V.A., Likhosherstov, L.M., Novikova, O.S. et al. Stability of O-glycoside linkages of O-maltoside and O-melibioside derivatives of serine in acid and alkaline media. Russ Chem Bull 20, 2122–2127 (1971). https://doi.org/10.1007/BF00851263

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  • DOI: https://doi.org/10.1007/BF00851263

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