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Reaction of ketoalcohols with organophosphorus compounds

Communication 5. Reaction of β-ketoalcohols with chlorophosphines

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reaction ofβ-ketoalcohols with chlorophosphines in the absence of organic bases leads to the formation of tertiary phosphine oxides.

  2. 2.

    A scheme for the reaction ofβ-ketoalcohols with chlorophosphines was proposed on the basis of the IR spectral data and the structure of the end products.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    F. S. Mukhametov, N. I. Rizpolozhenskii & É. I. Gol'dfarb

Authors
  1. F. S. Mukhametov
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  2. N. I. Rizpolozhenskii
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  3. É. I. Gol'dfarb
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2221–2225, October, 1971.

The authors express their gratitude to R. B. Nigmatullina for taking the IR spectra.

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Mukhametov, F.S., Rizpolozhenskii, N.I. & Gol'dfarb, É.I. Reaction of ketoalcohols with organophosphorus compounds. Russ Chem Bull 20, 2099–2102 (1971). https://doi.org/10.1007/BF00851258

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  • DOI: https://doi.org/10.1007/BF00851258

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