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Conformational analysis in a series of dichlorides of substituted phenylphosphoric acids

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The IR spectra of certain dichlorides of substituted phenylphosphoric acids were obtained. The presence of a dynamic equilibrium of rotational isomers was established.

  2. 2.

    The dipole moments were determined. The moments were calculated for various configurations.

  3. 3.

    For the compounds studied, trans- and checkerboard forms are realized.

  4. 4.

    An attempt was made at a quantitative evaluation of the factors influencing the isomeric equilibrium.

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Literature cited

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    O. A. Raevskii & F. G. Khalitov

Authors
  1. O. A. Raevskii
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  2. F. G. Khalitov
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2177–2181, October, 1971.

The authors would like to express their deep gratitude to R. R. Shagidullin for his valuable suggestions on the work and P. I. Alimov and F. G. Valitova for providing the materials.

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Raevskii, O.A., Khalitov, F.G. Conformational analysis in a series of dichlorides of substituted phenylphosphoric acids. Russ Chem Bull 20, 2058–2062 (1971). https://doi.org/10.1007/BF00851249

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  • DOI: https://doi.org/10.1007/BF00851249

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