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Study of complexes of metals with certain bidentate sulfur-containing ligands by the method of IR spectroscopy in the region of vibrations of the metal-sulfur bonds

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The IR spectra were studied in the region of the vibrations of the metal-sulfur bond for O,O′-diethyldithiophosphate, O-ethylxanthogenate, and N,N-diethyldithiocarbamate complexes of Zn(II), Cd(II), Hg(II), Pb(II), and Ni(II).

  2. 2.

    An empirical assignment of the bands corresponding to the valence vibrations of the metal-sulfur bonds (v M-S) was made.

  3. 3.

    The frequenciesv M-S were compared with the stability constants of the compounds studied. The increase in the stability of the chelates in the series of ligands diethyldithiophosphate < ethylxanthogenate < diethyldithiocarbamate is correlated with the increase in the frequency of the valence vibration of the metal-sulfur bond.

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Literature cited

  1. D. M. Adams, Metal-Ligand and Related Vibrations, E. Arnold Ltd., London (1967), p. 316.

    Google Scholar 

  2. K. Nakamoto, J. Fujita, R. A. Condrate, and J. Morimoto, J. Chem. Phys.,39, 423 (1963).

    Google Scholar 

  3. A. H. Ewald, R. L. Martin, T. G. Ross, and A. H. White, Proc. Roy. Soc., A280, 235 (1964).

    Google Scholar 

  4. D. C. Bradley and M. H. Gitlitz, J. Chem. Soc., A, 1152 (1969).

    Google Scholar 

  5. G. W. Watt and B. J. McCormick, Spectrochim. Acta,21, 753 (1965).

    Google Scholar 

  6. S. H. H. Chaston, S. E. Lyvingstone, T. N. Lockyer, V. A. Pickles, and J. S. Shannon, Austral. J. Chem.,18, 673 (1965).

    Google Scholar 

  7. D. M. Adams and J. B. Cornell, J. Chem. Soc., A, 1299 (1968).

    Google Scholar 

  8. N. P. Evtushenko, Ukr. Khim. Zh., 618 (1965).

  9. M. Franzini, Z. Kristallogr.,118, 393 (1963).

    Google Scholar 

  10. E. A. Shugat and V. M. Agre, Tr. Vses. N.-I In-ta Khim. Reaktivov i Osobo Chistykh Veshchestv,30, 364 (1967).

    Google Scholar 

  11. H. M. Rietveld and E. H. Maslen, Acta Crystallogr.,18, 429 (1965).

    Google Scholar 

  12. H. Hagihara and S. Yamasita, Acta Crystallogr.,21, 350 (1966).

    Google Scholar 

  13. T. Ikeda and H. Hagihara, Acta Crystallogr.,21, 350 (1966).

    Google Scholar 

  14. M. Bonamico, G. Dessy, C. Mariani, A. Vaciago, and L. Zambonelli, Acta Crystallogr.,19, 619 (1965).

    Google Scholar 

  15. M. Bonamico, G. Mazzone, A. Vagiano, and L. Zambonelli, Acta Crystallogr.,19, 898 (1965).

    Google Scholar 

  16. G. S. Zhdanov, Z. V. Zvonkova, and N. V. Raniev, Kristallografiya,1, 514 (1956).

    Google Scholar 

  17. A. Domeniscano, L. Torelli, A. Vaciago, and L. Zambonelli, J. Chem. Soc., A, 1351 (1968).

    Google Scholar 

  18. Z. V. Zvonkova, A. N. Khvatkina, and N. S. Ivanova, Kristallografiya,12, 1065 (1967).

    Google Scholar 

  19. E. A. Shugam and V. M. Agre, Kristallografiya,13, 253 (1968).

    Google Scholar 

  20. Q. Fernando and C. D. Green, J. Inorg. and Nucl. Chem.,29, 647 (1967).

    Google Scholar 

  21. J. F. McConnel and V. Kastalsky, Acta Crystallogr.,22, 853 (1967).

    Google Scholar 

  22. L. Lawton and G. T. Kokotailo, Nature,221, 550 (1969).

    Google Scholar 

  23. K. Nakamoto, Infrared Spectra of Inorganic and Coordination Compounds [Russian translation], Mir (1966), p. 297.

  24. V. F. Toropova, M. K. Saikina, and R. Sh. Aleshov, Zh. Obshch. Khim.,37, 725 (1967).

    Google Scholar 

  25. P. S. Shetty and Q. Fernando, J. Inorg. and Nucl. Chem.,29, 1921 (1967).

    Google Scholar 

  26. S. V. Larionov, V. M. Shul'man, and L. A. Podol'skaya, Zh. Neorgan. Khim.,12, 2457 (1967).

    Google Scholar 

  27. V. M. Shulman, T. V. Kramaryova, S. V. Larionov, and V. I. Dubinskij, Proc. 10 Internat. Conference Coordinat. Chem., Tokoyo-Nikko, 1967, Abstracts Papers, Tokyo Chem. Soc., Japan (1967), p. 63.

    Google Scholar 

  28. M. Hiroshi, Scient. Repts. Res. Inst. Tohoku Univ.,A13, 433 (1961).

    Google Scholar 

  29. K. Hiroshi and H. Kenjiro, J. Electrochem. Soc.,14, 209 (1967).

    Google Scholar 

  30. T. Yamasaki and M. Nanjo, Chemistry and Industry, 1530 (1966).

  31. M. Nanjo and T. Yamasaki, Chemistry and Industry, 1454 (1967).

  32. V. M. Shul'man, S. V. Larionov, and L. A. Podol'skaya, Izv. Sibirsk. Otd. Akad. Nauk SSSR, Ser. Khim. Nauk,3, 154 (1967).

    Google Scholar 

  33. A. Hulanicki, Talanta,14, 1371 (1967).

    Google Scholar 

  34. F. M. Tulyupa, L. M. Tkacheva, and Yu. I. Usatenko, Zh. Neorgan. Khim.,13, 2058 (1968).

    Google Scholar 

  35. F. M. Tulyupa, Yu. I. Usatenko, and V. S. Barkelov, Zh. Neorgan. Khim.,13, 3227 (1968).

    Google Scholar 

  36. F. M. Tulyupa, L. M. Tkacheva, V. A. Pavlichenko, and Yu. A. Usatenko, Izv. Vyssh. Uchebn. Zav. Khimiya i Khim. Tekhnologiya,11, No. 11, 1219 (1968).

    Google Scholar 

  37. O. Budevsky, E. Russeva, and T. Sotyrova, Talanta,15, 629 (1968).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Inorganic Chemistry, Siberian Branch of the Academy of Sciences of the USSR, USSR

    I. M. Cheremisina & S. V. Larionov

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  1. I. M. Cheremisina
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  2. S. V. Larionov
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2150–2155, October, 1971.

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Cheremisina, I.M., Larionov, S.V. Study of complexes of metals with certain bidentate sulfur-containing ligands by the method of IR spectroscopy in the region of vibrations of the metal-sulfur bonds. Russ Chem Bull 20, 2032–2036 (1971). https://doi.org/10.1007/BF00851244

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  • DOI: https://doi.org/10.1007/BF00851244

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