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The adsorption effects in gas-liquid chromatography on columns with mixed stationary gases

  • Physical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Adsorption effects produce a sharp increase in the absolute characteristics of the retention of polar compounds and a decrease in the efficiency of the column when small amounts of tricresyl phosphate are added to a sorbent containing squalane on Chromosorb-P.

  2. 2.

    The values of the relative coefficient of adsorption of polar compounds on the surface of a polar liquid were determined on the basis of the graphical dependence of the absolute characteristics of retention on the composition of the binary sorbent.

  3. 3.

    The relative values of the diffusion coefficients of sorbates in the liquid phase were determined.

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    V. I. Pakhomova & M. S. Vigdergauz

Authors
  1. V. I. Pakhomova
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  2. M. S. Vigdergauz
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 10, pp. 2135–2140, October, 1971.

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Pakhomova, V.I., Vigdergauz, M.S. The adsorption effects in gas-liquid chromatography on columns with mixed stationary gases. Russ Chem Bull 20, 2020–2023 (1971). https://doi.org/10.1007/BF00851241

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  • DOI: https://doi.org/10.1007/BF00851241

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