Distribution of adsorbed molecules along zeolitecavities

  • V. A. Bakaev
  • I. A. Kalinnikova
  • V. V. Serpinskii
Brief Communications


From the experimental isotherm of adsorption on a zeolite, on the assumption of a quasiindependence of the molecules found in different cavities, it is possible to determine the distribution of the adsorbed molecules along the zeolite cavities. If the adsorption isotherm satisfies the Henry equation, then this distribution coincides with the Poisson distribution, while if it satisfies the Langmuir equation then the distribution coincides with the Bernoulli distribution.


Zeolite Adsorption Isotherm Poisson Distribution Bernoulli Distribution Adsorbed Molecule 
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Literature cited

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    V. A. Bakaev, Dokl. Akad. Nauk SSSR, 167, 369 (1966).Google Scholar
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    A. A. Lopatkin and G. R. Stepanets, in: Papers Delivered at Second International Conference on Zeolites, Washington (1970).Google Scholar
  3. 3.
    W. Feller, Introduction to the Theory of Probabilities and Its Applications [Russian translation], IL (1952), pp. 123, 106.Google Scholar
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    A. M, Arkharov, B. P. Bering, I. A. Kalinnikova, and V. V. Serpinskii, Izv. Akad. Nauk SSSR, Ser. Khim., 1434 (1972).Google Scholar
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    I. A. Kalinnikova, Dissertation [in Russian], Moscow (1972).Google Scholar

Copyright information

© Consultants Bureau 1973

Authors and Affiliations

  • V. A. Bakaev
    • 1
  • I. A. Kalinnikova
    • 1
  • V. V. Serpinskii
    • 1
  1. 1.Institute of Physical ChemistryAcademy of Sciences of the USSRUSSR

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