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Solubility diagram of system: Csalh4-dimethyl ether-diethylene glycol

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the reaction in the system CsAlH4-diglyme in the interval from −65 to 50°.

  2. 2.

    The crystallization region of the unsolvated cesium aluminum hydride was determined, and the existence of a CsAlH4 solvate was established, which melts incongruently at −23°.

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Literature cited

  1. S. I. Bakum and T. N. Dymova, Izv. Akad. Nauk SSSR, Ser. Khim., 1890 (1970).

  2. T. N. Dymova, S. I. Bakum, S. S. Grazhulene, and M. Mukhidinov, Izv. Akad. Nauk SSSR, Ser. Khim., 1892 (1970).

  3. S. I. Bakum, U. Mirsaidov, M. E. Kost, and T. N. Dymova, Izv. Akad. Nauk SSSR, Ser. Khim., 2108 (1972).

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.2, pp.440–441, February, 1973.

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Bakum, S.I., Mirsaidov, U. & Dymova, T.N. Solubility diagram of system: Csalh4-dimethyl ether-diethylene glycol. Russ Chem Bull 22, 418–419 (1973). https://doi.org/10.1007/BF00851004

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  • DOI: https://doi.org/10.1007/BF00851004

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