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Some characteristics of telomerization of propylene and ethylene with CCl4, initiated by iron pentacarbonyl

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

In the Fe(CO)5-catalyzed telomerization of propylene with CCl4 at 105°, it was found that the reaction time affects the distribution of the telomer homologs (at low conversions of the reactants). The composition of the products in the telomerization of ethylene with CCl4 is independent of either changes in the Fe(CO)5 concentration or the reaction time. The possible reasons for these effects are discussed.

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    R. Kh. Freidlina, N. A. Grigor'ev & B. A. Englin

Authors
  1. R. Kh. Freidlina
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  2. N. A. Grigor'ev
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  3. B. A. Englin
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.2, pp.338–343, February, 1973.

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Freidlina, R.K., Grigor'ev, N.A. & Englin, B.A. Some characteristics of telomerization of propylene and ethylene with CCl4, initiated by iron pentacarbonyl. Russ Chem Bull 22, 323–327 (1973). https://doi.org/10.1007/BF00850984

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  • DOI: https://doi.org/10.1007/BF00850984

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