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Effect of nature of solvent on rate and distribution of products in the telomerization of propylene with CCl4, catalyzed by iron pentacarbonyl

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    A study was made of the distribution of the telomer homologs and initial telomerization rates of propylene with CCl4 when catalyzed by iron pentacarbonyl in the presence of n-C6H14, CH3CN, CH3OH, i-C3H7OH, t-C4H9OH, and HCON(CH3)2 at 105°.

  2. 2.

    The probability of a catalytic transfer of the chlorine atom via the intermediate iron compounds increases with increase in the capacity of the solvent to coordinate with the metal atom. The overall telomerization rate depends on the dielectric constant of the solvent. A possible mechanism for the effect exerted by the nature of the solvent is discussed.

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Literature cited

  1. R. Kh. Freidlina, B. N. Osipov, and B. A. Énglin, Izv. Akad. Nauk SSSR, Ser. Khim., 2511 (1970).

  2. R. Kh. Freidlina, N. A. Grigor'ev, and B. A. Énglin, Izv. Akad. Nauk SSSR, Ser. Khim., 338 (1973).

  3. C. H. Bamford and G. C. Eastmond, Pure Appl. Chem.,12, 183 (1966); C. H. Bamford, J. Appl. Chem., 13, 525 (1963).

    Google Scholar 

  4. C. H. Bamford and K. Hargreaves, Proc. Roy. Soc. (London),A297, 425 (1967).

    Google Scholar 

  5. C. H. Bamford, R. Denyer, and G. C. Eastmond, Trans. Faraday Soc.,62, 688 (1966); Z. Naturforsch.,22b, 580 (1967); C. H. Bamford, G. C. Eastmond, and D. Whittle, J. Org. Chem.,17, P33 (1969); C. H. Bamford, G. C. Eastmond, and E. J. T. Fildes, Chem. Commun., 144 (1970).

    Google Scholar 

  6. C. H. Bamford, G. C. Eastmond, and K. Hargreaves, Trans. Faraday Soc.,64, 175 (1968).

    Google Scholar 

  7. M. Asher and D. Vofsi, Zh. Organ. Khim.,2, 377 (1966).

    Google Scholar 

  8. R. Kh. Freidlina, E. Ts. Chukovskaya, and B. A. Énglin, Dokl. Akad. Nauk SSSR,159, 1346 (1964); Zh. Organ. Khim.,2, 378 (1966).

    Google Scholar 

  9. E. Ts. Chukovskaya, N. A. Kuz'mina, and R. Kh. Freidlina, Izv. Akad. Nauk SSSR, Ser. Khim., 1198 (1969).

  10. V. Gutman, Coordination Chem. Rev.,2, 239 (1967); Chemistry in Britain,7, 102 (1971).

    Google Scholar 

  11. P. P. Singh and R. Rivest, Canad. J. Chem.,46, 1773 (1968).

    Google Scholar 

  12. H. Werner, Angew. Chem., Internat. Edit.,7, 930 (1968); R. J. Angelici, Organometal. Chem. Rev.,3, 173 (1968).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, USSR

    B. A. Énglin, N. A. Grigor'ev & R. Kh. Freidlina

Authors
  1. B. A. Énglin
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  2. N. A. Grigor'ev
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  3. R. Kh. Freidlina
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.2, pp. 333–338, February, 1973.

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Énglin, B.A., Grigor'ev, N.A. & Freidlina, R.K. Effect of nature of solvent on rate and distribution of products in the telomerization of propylene with CCl4, catalyzed by iron pentacarbonyl. Russ Chem Bull 22, 318–322 (1973). https://doi.org/10.1007/BF00850983

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  • DOI: https://doi.org/10.1007/BF00850983

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