Conclusions
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1.
The thermochemical characteristics were determined experimentally and the energies of the nitrogen-nitrogen bonds calculated for certain alkyl- and polynitroalkyl-N-nitrosoamines and the corresponding N-nitroamines.
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2.
The energy of the nitrogen-nitrogen bond in N-nitrosoamines may vary in the range 40–55 kcal, depending on the electronegativity of the substituent at the amino nitrogen atom.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.2, pp. 318–322, February, 1973.
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Pepekin, V.I., Gafurov, R.G., Lebedev, Y.A. et al. Thermochemistry of N-nitrosoamines. Russ Chem Bull 22, 304–307 (1973). https://doi.org/10.1007/BF00850979
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DOI: https://doi.org/10.1007/BF00850979