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Study of the interaction of perchlorates with anhydrous perchloric acid by the PMR method

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    Solutions of potassium, rubidium, cesium, and tetrabutylammonium perchlorate in anhydrous perchloric acid were investigated by the PMR method. A linear dependence of the chemical shift of the proton in the weak-field direction on the molar concentration of perchlorate was detected. An analogous dependence exists in solutions of (C4H9)4NClO4-HClO4 in chloroform.

  2. 2.

    HClO4 molecules form the anion H(ClO4) s−2 with perchlorates through a hydrogen bond. Evidently the dissociation of the biperchlorate anion in solution is negligible.

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Authors and Affiliations

  1. Institute of New Chemical Problems, Academy of Sciences of the USSR, USSR

    Z. I. Grigorovich, Yu. I. Malov & V. Ya. Rosolovskii

Authors
  1. Z. I. Grigorovich
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  2. Yu. I. Malov
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  3. V. Ya. Rosolovskii
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No.2, pp.265–269, February, 1973.

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Grigorovich, Z.I., Malov, Y.I. & Rosolovskii, V.Y. Study of the interaction of perchlorates with anhydrous perchloric acid by the PMR method. Russ Chem Bull 22, 257–260 (1973). https://doi.org/10.1007/BF00850968

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  • DOI: https://doi.org/10.1007/BF00850968

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