Summary
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1.
The structure was established of gypsoside, the gypsogenin glycoside isolated from the roots ofGypsophila pacifica.
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2.
Arguments are advanced in favor of the existence of gypsoside in two forms-in the form of the acid and of the hemiacylal resulting from interaction between the carboxy group of the glucuronic acid residue and the aldehyde group of gypsogenin.
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Infrared spectra were determined by S. L. Pormova and V. A. Krasnova, whom the authors thank.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 8 pp. 1436–1446, August, 1964
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Kochetkov, N.K., Khorlin, A.Y. & Ovodov, Y.S. Triterpenoid saponins. Communication 9. Structure of gypsoside. Russ Chem Bull 13, 1345–1353 (1964). https://doi.org/10.1007/BF00850332
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DOI: https://doi.org/10.1007/BF00850332