Reaction of hydrogen chloride with halides of quaternary ammonium salts
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The solubility of (n-C4H9)4NCl and (n-C4H9)4NBr in benzene was determined at 25°.
The interaction of gaseous HCl with tetra-substituted ammonium halides was investigated. A decrease in the dimensions of the anion and an increase in the dimensions of the cation promote interaction.
The behavior of the reaction products of HCl with tetra-substituted ammonium halides in benzene was investigated. In the case of salts sparingly soluble in benzene, the presence of a correlation between the aggregated state of the reaction products of HCl with the salts at 25° and their solubility in benzene at the same temperature was established.
KeywordsHydrogen Chloride Ammonium Benzene Halide
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