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Heat capacity at low temperatures, phase transitions, entropy and enthalpy of rubidium hyperperoxide

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The authors have synthesized RbO2 (99.8%) by roasting Rb in a current of an argon-oxygen mixture.

  2. 2.

    The heat capacities of RbO2 have been determined in a vacuum adiabatic calorimeter in the range 12.9–297.8°K, and anomalies observed at 15 and 178.3°K.

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Literature cited

  1. I. E. Paukov and F. S. Rakhmenkulov, Zh. Fiz. Khim.,43, 788 (1969).

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  2. Mean Standard Table SST-64 [in Russian], Izd-vo Standartov (1965).

  3. I. I. Vol'nov and V. V. Matveev, Investigations in the Fields of Chemistry and Technology of Mineral Salts and Oxides [in Russian], Nauka(1965), p. 303.

  4. A. B. Tsentsiper and M. S. Dobrolyubova, Izv. Akad. Nauk SSSR, Ser. Khim., 175 (1968).

  5. G. D. Smith et al., International Union of Crystallographers, Seventh International Congress and Symposium on Crystal Growth; Abstracts of Reports [Russian translation], Nauka (1966), p. 194.

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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2135–2138, September, 1970.

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Paukov, I.E., Rakhmenkulov, F.S., Dobrolyubova, M.S. et al. Heat capacity at low temperatures, phase transitions, entropy and enthalpy of rubidium hyperperoxide. Russ Chem Bull 19, 2015–2017 (1970). https://doi.org/10.1007/BF00849798

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  • DOI: https://doi.org/10.1007/BF00849798

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