Conclusions
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1.
A method has been developed for GLC analysis of the reaction mixture formed by the vinylation of triethanolamine; the method can be used while carrying out the processes of synthesis and separation of the vinyl ethers of triethanolamine.
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2.
By combining the chemical and GLC analysis of this reaction mixture the presence of anomalous products of the conversion of triethanolamine under vinylation conditions has been demonstrated; these products are the mono- and divinyl ethers of diethanolamine and the vinyl ether of N-hydroxyethylmorpholine; the total content of these is 14–20% and is dependent on the conditions for carrying out the process.
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2116–2118, September, 1970.
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Ostrovskii, S.A., Ustynyuk, L.A., Kononov, N.F. et al. Conversion products from triethanolamine under vinylation reaction conditions and their analysis. Russ Chem Bull 19, 1990–1992 (1970). https://doi.org/10.1007/BF00849788
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DOI: https://doi.org/10.1007/BF00849788