Conclusions
-
1.
Dichloro-(C-isopropylcarboranyl)borane was prepared by the action of boron trichloride on C-iso-propylcarboranyllithium.
-
2.
By the action of methanol, mercaptans or amines on dichloro-(C-isopropylcarboranyl)borane the corresponding methoxy, alkyl mercapto, and amino derivatives of the boron carborane compounds have been synthesized.
-
3.
The boron-carbon bond in organoboron compounds of the carborane series undergoes splitting under the action of an excess of alcohol.
This is a preview of subscription content, log in via an institution to check access.
Similar content being viewed by others
Literature cited
B. M. Mikhailov, The Chemistry of the Boranes [in Russian], Izd. Nauka (1967).
W. E. Davidsohn and M. C. Henry, Chem. Rev.,67, 73 (1967).
J. L. Boone, R. J. Brotherton, and L. L. Petterson, Inorgan. Chem.,4, 910 (1965).
B. M. Mikhailov, T. K. Kozminskaya, N. S. Fedotov, and V. A. Dorokhov, Dokl. Akad. Nauk SSSR,127, 1023 (1959).
Author information
Authors and Affiliations
Additional information
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2048–2052, September, 1970.