Conclusions
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1.
The IR absorption spectra of complexes with the composition M2Ni(NCS)4·nH2O and MM′Ni(NCS)4 ·nH2O, where M and M′=Na, K, Cs, NH4, [C(NH2)3], 1/2Ba, n=0–7, were studied.
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2.
In all the investigated complexes, with the exception of the cesium salts, both bridge NCS groups and groups coordinated through the nitrogen atoms are present. In the cesium salts, the presence of nonbridge isothiocyanate groups is noted.
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The article is published on the basis of a resolution of the Conference of Editors-in-Chief of the Journals of the Academy of Sciences of the USSR from June 12, 1962 as the dissertation work of A. Yu. Tsivadze.
Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 2002–2006, September, 1970.
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Tsivadze, A.Y., Kharitonov, Y.Y. & Tsintsadze, G.V. Infrared absorption spectra of tetrathiocyanate complexes of nickel. Russ Chem Bull 19, 1883–1886 (1970). https://doi.org/10.1007/BF00849765
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DOI: https://doi.org/10.1007/BF00849765