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Electrochemical reduction of bifunctional organic compounds

Communication 3. Quantitative evaluation of the rate of conversion of endiol to ketol in the reduction of p-dibenzoylbenzene

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The rearrangement of an endiol formed in the reduction of p-dibenzoylbenzene, to a ketol was studied quantitatively.

  2. 2.

    It was found by a polarographic method that the hydroxonium ion is 2.22·108 times as effective an electrophilic reagent with respect to the C atom of the enolate ion as H2O.

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Literature cited

  1. P. Zuman, Advances in Physical Organic Chemistry, Vol.5, Academic Press, New York (1967), p. 1.

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  2. D. Hawley and R. N. Adams, J. Electroanal. Chem.,10, 376 (1965).

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  3. R. S. Nicholson, J. M. Wilson, and M. L. Olmstead, Analyt. Chem.,38, 542 (1966).

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  4. Yu. M. Kargin, V. Z. Kondranina, and R. T. Safin, Izv. Akad. Nauk SSSR, Ser. Khim., 1264 (1970).

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Authors and Affiliations

  1. A. E. Arbuzov Institute of Organic and Physical Chemistry, Academy of Sciences of the USSR, USSR

    Yu. M. Kargin & V. Z. Kondranina

Authors
  1. Yu. M. Kargin
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  2. V. Z. Kondranina
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 9, pp. 1976–1979, September, 1970.

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Kargin, Y.M., Kondranina, V.Z. Electrochemical reduction of bifunctional organic compounds. Russ Chem Bull 19, 1859–1861 (1970). https://doi.org/10.1007/BF00849760

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  • DOI: https://doi.org/10.1007/BF00849760

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