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Study of the thermodynamic properties of solutions of strong electrolytes in solvents with high dielectric constants

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The activity coefficients of NaCl in formamide and KCl in N-methylformamide were measured at 25°.

  2. 2.

    The change in the free energy of solvation of the ions was determined upon their transfer from water to the indicated solvent at infinite dilution.

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Literature cited

  1. Yu. M. Povarov, Yu. M. Kessler, A. I. Gorbanev, and I. V. Safonova, Dokl. AN SSSR,155, 172 (1964).

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  3. R. Robinson and R. Stokes, Solutions of Electrolytes [Russian translation], Izd-vo Inostr. Lit., Moscow, p. 279 (1963).

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Authors and Affiliations

  1. Institute of Electrochemistry, Academy of Sciences, USSR

    Yu. M. Povarov, Yu. M. Kessler & A. I. Gorbanev

Authors
  1. Yu. M. Povarov
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  2. Yu. M. Kessler
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  3. A. I. Gorbanev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seria Khimicheskaya, No. 10, pp. 1895–1896, October, 1964

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Povarov, Y.M., Kessler, Y.M. & Gorbanev, A.I. Study of the thermodynamic properties of solutions of strong electrolytes in solvents with high dielectric constants. Russ Chem Bull 13, 1800–1801 (1964). https://doi.org/10.1007/BF00849458

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  • DOI: https://doi.org/10.1007/BF00849458

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