Conclusions
Methyltrichlorogermane, bis(trichlorogermyl)methane, and Ge-hexachloro-1,3,5-germacyclohexane are formed in good yield from dichloromethane and elementary germanium in a flow-type setup at 380°.
Literature cited
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Additional information
Let us thank L. A. Leites for taking the IR and Raman spectra and A. N. Egorochkin for the NMR spectra.
Translated from Izvestiya Akademii Nauk SSSR, Seria Khimicheskaya, No. 10, pp. 1887–1889, October, 1964
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Mironov, V.F., Gar, T.K. Interaction of dichloromethane with germanium. Russ Chem Bull 13, 1790–1792 (1964). https://doi.org/10.1007/BF00849454
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DOI: https://doi.org/10.1007/BF00849454