Conclusions
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1.
The radical products in irradiated frozen solutions of KOH in H2O and D2O were investigated by the electron paramagnetic resonance method at various concentrations and in the temperature range from −196 to −100°.
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2.
Stabilization of the hydrated electron and conversion of the OH radical to the ion radical O− · nH2O occur in alkaline medium.
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3.
H and D atoms were detected in irradiated concentrated frozen solutions of KOH in H2O and D2O at −196°
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4.
The thermal stability of the radical products in neutral water and in solutions of alkali of various concentrations was investigated.
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5.
The yields of radical products in alkaline medium were determined at temperatures of −196 and −150° as a function of the KOH concentration, and they were found to be increased in comparison with neutral frozen water.
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Translated from Izvestiya Akademii Nauk SSSR, Seria Khimicheskaya, No. 10, pp. 1755–1761, October, 1964
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Ershov, B.G., Pikaev, A.K., Glazunov, P.Y. et al. Electron paramagnetic resonance spectra of irradiated frozen aqueous solutions Communication 1. Solutions of alkalis. Russ Chem Bull 13, 1667–1671 (1964). https://doi.org/10.1007/BF00849426
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DOI: https://doi.org/10.1007/BF00849426