Conclusions
On the example of the reduction of the selenious salts of Cu, Cd, Co and Ni it was shown that selenides of stoichiometric composition can be obtained by the reduction of selenites with sodium hydrosulfite in alkaline medium.
Literature cited
L. A. Chugaev and V. G. Khlopin, Zh. Russ. Fiz.-Khim. Obshchestva46, 185 (1914);47, 364 (1915).
W. M. Latimer, The Oxidation States of the Elements and Their Potentials in Aqueous Solutions [Russian translation], IL, Moscow, 1954.
V. M. Shul'man and A. V. Popova, Collection of Abstracts of Scientific Research Papers on Luminophors [in Russian], p. 26, NTI GIPKh, 1957.
V. G. Chukhlantsev, Zh. Neorgan. Khimii1, 2300 (1956).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 934–935, May, 1966.
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Shul'man, V.M., Varand, V.L. Preparation of selenides of copper, cadmium, cobalt and nickel by the reduction of selenites in aqueous solutions. Russ Chem Bull 15, 895–896 (1966). https://doi.org/10.1007/BF00849399
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DOI: https://doi.org/10.1007/BF00849399