Effect of substituents in the carbocyclohexyloxy group on the rate of its cleavage during hydrobrominolysis

  • K. T. Poroshin
  • V. A. Shibnev
  • A. V. Lisovenko
  • V. C. Grechishko
Brief Communications

Conclusions

  1. 1.

    A number of o-methylcarbocyclohexyloxyamino acids and 3,3,5-trimethylcarbocyclohexyloxyglycine were synthesized.

     
  2. 2.

    The use of the o-methylcarbocyclohexyloxy group as a mixture of isomers leads to a reduction in the hydrobrominolysis rate when compared with the carbocyclohexyloxy group.

     
  3. 3.

    The presence of three methyl groups in the 3,3,5 position in the cyclohexane ring of the carbocyclohexyloxy group increases the hydrobrominolysis rate when compared with the carbocyclohexyloxy group.

     

Keywords

Methyl Cyclohexane Cyclohexane Ring 

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Literature cited

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Copyright information

© Consultants Bureau 1967

Authors and Affiliations

  • K. T. Poroshin
    • 1
    • 2
  • V. A. Shibnev
    • 1
    • 2
  • A. V. Lisovenko
    • 1
    • 2
  • V. C. Grechishko
    • 1
    • 2
  1. 1.Institute of Biological PhysicsAcademy of Sciences of the USSRUSSR
  2. 2.Institute of ChemistryAcademy of Sciences of the TadzSSRUSSR

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