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Highly unsaturated polymers Communication 16. Polyacetylene compounds derived from di- and tri-phenylmethanes, 1,1-diphenylmethane, and bibenzyl

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    To determine ways of synthesizing soluble highly unsaturated polymers 1,1-bis(p-ethynylphenyl)-ethane was synthesized. The oligomer formed by its oxidative condensation is soluble in pyridine.

  2. 2.

    The oligomer obtained by the polycondensation of tris(p-ethynylphenyl)methane gives an intense narrow ESR signal, despite the formal interruption of the conjugation in the oligomer chain.

  3. 3.

    As monomers a number of mono-, di-, and tri-acetylenes derived from diphenylmethane and dibenzyl were prepared.

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Literature cited

  1. I. L. Kotlyarevskii, A. S. Zanina, and S. I. Shergina, Izv. AN SSSR. Ser. khim.1963, 2197.

  2. M. S. Shvartsberg, I. L. Kotlyarevskii, V. N. Andrievskii, and S. F. Vasilevskii, Izv. AN SSSR. Ser. khim.1966, 527.

  3. R. E. Lutz, R. K. Allison, G. A. Ashburn, P. S. Bailey, and M. T. Clark, J. Organ. Chem.12, 617 (1947).

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Authors and Affiliations

  1. Institute of Chemical Kinetics and Combustion, Siberian Division, Academy of Sciences of the USSR, USSR

    I. L. Kotlyarevskii, A. S. Zanina, S. I. Shergina & L. I. Loboda

Authors
  1. I. L. Kotlyarevskii
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  2. A. S. Zanina
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  3. S. I. Shergina
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  4. L. I. Loboda
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 902–908, May, 1966.

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Kotlyarevskii, I.L., Zanina, A.S., Shergina, S.I. et al. Highly unsaturated polymers Communication 16. Polyacetylene compounds derived from di- and tri-phenylmethanes, 1,1-diphenylmethane, and bibenzyl. Russ Chem Bull 15, 862–866 (1966). https://doi.org/10.1007/BF00849388

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  • DOI: https://doi.org/10.1007/BF00849388

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