Conclusions
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1.
Amides of phenylvinylphosphinic acid and the ethyleneimide of phenyl-β-chloroethylphosphinic acid were produced.
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2.
The IR spectra of the substances obtained were studied. On the basis of the values of the frequencies of the P=O and C=C groups, the presence of pπ-dπ-conjugation in the systems considered was hypothesized.
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3.
The rate of inversion of nitrogen in the ethyleneimides of phenylvinylphosphinic and phenyl-β-chloroethylphosphinic acids, according to the PMR data, is very high.
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Literature cited
P. Mastalerz, Roczn. Chem.,34, 1161 (1960).
E. L. Gefter and I. A. Rogacheva, Zh. Obshch. Khimii,31, 955 (1961).
M. I. Kabachnik, T. A. Mastryukova, and T. A. Melent'eva, Zh. Obshch. Khimii,33, 382 (1963).
L. W. Daasch and D. C. Smith, Anal. Chem.,23, 853 (1951).
A. T. Bottini and J. D. Roberts, J. Amer. Chem. Soc.,80, 5203 (1958).
R. G. Kostyanovskii and V. F. Bystrov, Dokl. AN SSSR,148, 839 (1963).
J. A. Pople, W. G. Schneider, and H. J. Bernstein, High-Resolution Nuclear Magnetic Resonance Spectra [Russian translation], IL., Moscow (1962).
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 5, pp. 839–843, May, 1966.