Equilibrium double-layer capacitance at the metal-binary electrolyte interface

  • A. A. Chernenko
Physical Chemistry
  • 29 Downloads

Conclusions

  1. 1.

    A method has been proposed for calculating the differential capacitance of the equilibrium electrode in the general case, i. e., when the exchange current is not necessarily equal to zero.

     
  2. 2.

    An approximate formula was found for the capacitance of the equilibrium electrode, and its relationship to the electrochemical conductivity of the system was established.

     
  3. 3.

    The capacitance of the equilibrium electrode in general may differ substantially from the capacitance of the ideally polarized electrode for the same parameters of the solution.

     

Keywords

Approximate Formula Exchange Current Electrolyte Interface Differential Capacitance Equilibrium Electrode 

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Literature cited

  1. 1.
    B. M. Grafov and A. A. Chernenko, Dokl. AN SSSR,146, 135 (1962).Google Scholar
  2. 2.
    A. N. Frumkin, V. S. Bagotskii, Z. A. Iofa, and B. N. Kabanov, Kinetics of Electrode Processes [in Russian], Izd. MGU, Moscow (1952).Google Scholar
  3. 3.
    L. S. Pontryagin, Normal Differential Equations [in Russian] (1961).Google Scholar
  4. 4.
    A. A. Chernenko, Dokl. AN SSSR,153, 1129 (1963).Google Scholar
  5. 5.
    G. M. Fikhtengol'ts, Course in Differential and Integral Calculus [in Russian], 1, OGIZ, Moscow-Leningrad (1948).Google Scholar

Copyright information

© Consultants Bureau 1967

Authors and Affiliations

  • A. A. Chernenko
    • 1
  1. 1.Institute of ElectrochemistryAcademy of Sciences of the USSRUSSR

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