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The formation of magnesium perperoxide Mg(O2)2 in the reaction of magnesium peroxide with ozone

  • I. I. Vol'nov
  • S. A. Tokareva
  • V. N. Belevskii
  • E. I. Latysheva
Inorganic and Analytical Chemistry

Conclusions

  1. 1.

    The possibility of the formation of a new perperoxide magnesium perperoxide Mg (O2)2 at −85 to −65° in the reaction of ozone, dissolved in Freon-12, with magnesium peroxide, suspended in the same medium, was demonstrated.

     
  2. 2.

    Preparations were isolated containing ∼60% Mg(O2)2. The individuality of magnesium perperoxide was confirmed by the EPR method. The limit of its thermal stability −35 to −29° was established by the method of differential thermal analysis.

     

Keywords

Peroxide Magnesium Ozone Thermal Stability Thermal Analysis 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Consultants Bureau 1970

Authors and Affiliations

  • I. I. Vol'nov
    • 1
  • S. A. Tokareva
    • 1
  • V. N. Belevskii
    • 1
  • E. I. Latysheva
    • 1
  1. 1.N. S. Kurnakov Institute of General and Inorganic ChemistryAcademy of Sciences of the USSRUSSR

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