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Interaction of molybdenum (V) oxotrichloride with certain aliphatic amines

  • Inorganic and Analytical Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The interaction of MoOCl3 with monoethyl-, dimethyl-, diethyl-, trimethyl-, and triethylamines was studied.

  2. 2.

    The reactions of MoOCl3 with primary and secondary alkylamines are accompanied by solvolysis at the molybdenum-chlorine bonds. Compounds with the composition MoOCl2NHC2H5; MoOCl2N(CH3)2; MoOCl[N(C2H5)2]2. were isolated.

  3. 3.

    As a result of the interaction of MoOCl3 with trimethyl- and triethylamines, compounds with the composition: MoOCl3·N(CH3)3 and MoOCl3·N(C2H5)3, respectively, are formed.

  4. 4.

    According to the IR spectra, the molybdenum-oxygen bonds in the compounds represent a ⋯Mo··OMoOMoO⋯ chain of increased multiplicity.

  5. 5.

    As a result of pyrolysis under vacuum or an inert atmosphere at 500–600°C, all the compounds isolated decompose to molybdenum dioxide.

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Literature cited

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Authors and Affiliations

  1. N. S. Kurnakov Institute of General and Inorganic Chemistry, Academy of Sciences of the USSR, USSR

    A. A. Kuznetsova, L. F. Goryachova & Yu. A. Buslaev

Authors
  1. A. A. Kuznetsova
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  2. L. F. Goryachova
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  3. Yu. A. Buslaev
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 3, pp. 509–513, March, 1970.

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Kuznetsova, A.A., Goryachova, L.F. & Buslaev, Y.A. Interaction of molybdenum (V) oxotrichloride with certain aliphatic amines. Russ Chem Bull 19, 464–467 (1970). https://doi.org/10.1007/BF00848958

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  • DOI: https://doi.org/10.1007/BF00848958

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