Alkylation of phenols with bifunctional compounds Communication 14. Catalytic alkylation of p-cresol with α-, γ-, and δ-epoxides

  • E. A. Viktorova
  • N. I. Shuikin
  • É. A. Karakhanov
Organic and Biological Chemistry
  • 23 Downloads

Conclusions

  1. 1.

    An investigation was made of the alkylation of p-cresol with α-, γ-, and δ-epoxides in presence of zinc chloride on alumina.

     
  2. 2.

    In the alkylation of p-cresol withα-epoxides only O-alkylation occurs with formation of 2-(p-tolyIoxy)-1-alkanols.

     
  3. 3.

    In the alkylation of p-cresol withγ- andδ-epoxides in presence of zinc chloride on alumina reaction requires relatively high temperatures (250 and 300°) and passes through the stage of dehydration of the epoxides into dienic hydrocarbons.

     

Keywords

Alumina Chloride Zinc Phenol Hydrocarbon 

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Copyright information

© Consultants Bureau 1967

Authors and Affiliations

  • E. A. Viktorova
    • 1
  • N. I. Shuikin
    • 1
  • É. A. Karakhanov
    • 1
  1. 1.M. V. Lomonosov Moscow State UniversityUSSR

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