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On the mechanism of the formation of barene in the oxidation of di (hydroxymethyl)-barene by potassium permanganate

  • L. I. Zakharkin
  • A. V. Kazantsev
Brief Communications
  • 31 Downloads

Conclusions

  1. 1.

    Oxidation of hydroxymethyl-derivatives of harenes, including di(hydroxymethyl)barene, by potassium permanganate to the corresponding barenes includes two steps: a) oxidation of the hydroxymethyl group to the formyl group and b) cleavage of the C-C bond in the barenic aldehyde under the action of alkali, forming the corresponding barene.

     
  2. 2.

    The oxidation of di(hydroxymethyl)neobarene to neobarene proceeds analogously.

     
  3. 3.

    A method was proposed for the synthesis ofα-barenic ketones by the oxidation of secondaryα-barenic alcohols with chromic mixture.

     
  4. 4.

    Oxidation of secondaryα-barenic alcohols by alkaline potassium permanganate is accompanied by cleavage of the C-C bond and leads to the corresponding barenes.

     

Keywords

Oxidation Alcohol Potassium Aldehyde Barene 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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Literature cited

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Copyright information

© Consultants Bureau 1967

Authors and Affiliations

  • L. I. Zakharkin
    • 1
  • A. V. Kazantsev
    • 1
  1. 1.Institute of Heteroorganic CompoundsAcademy of Sciences of the USSRUSSR

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