Alkenyl compounds of bismuth

  • A. E. Borisov
  • M. A. Osinova
  • A. N. Nesmeyanov
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Summary

  1. 1.

    Tri-(cis-) and tri-(trans-propenyl)bismuth and triisopropenylbismuth were synthesized. The configuration of the stereoisomers was established on the basis of the IR spectra.

     
  2. 2.

    These propenyl compounds of bismuth gave with bromine the corresponding tri-(cis-) and tri-(trans-propenyl)bismuth dibromide and isopropenylbismuth dibromide.

     
  3. 3.

    Triallylbismuth was obtained from the products of the reaction of allylmagnesium bromide and bismuth trichloride.

     

Keywords

Bromide Bismuth Bromine Trichloride Dibromide 

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Literature cited

  1. 1.
    A. N. Nesmeyanov, A. E. Borisov, and N. V. Novikova, Dokl. AN SSSR,119, 504 (1958).Google Scholar
  2. 2.
    A. N. Nesmeyanov, A. E. Borisov, and N. V. Novikova, Izv. AN SSSR, Otd. khim. n., 1216 (1959).Google Scholar
  3. 3.
    A. N. Nesmeyanov, A. E. Borisov, and N. V. Novikova, Izv. AN SSSR, Otd. khim. n., 147 (1960).Google Scholar
  4. 4.
    A. N. Nesmeyanov, A. E. Borisov, and N. V. Novikova, Izv. AN SSSR, Otd. khim. n., 612 (1961).Google Scholar
  5. 5.
    A. E. Borisov, A. N. Abramova, and A. N. Nesmeyanov, Izv. AN SSSR, Otd. khim. n., 1258 (1962).Google Scholar
  6. 6.
    A. E. Borisov, N. V. Novikova, and N. A. Chumaevskii, Dokl. AN SSSR,136, 130 (1961).Google Scholar

Copyright information

© Consultants Bureau 1964

Authors and Affiliations

  • A. E. Borisov
    • 1
  • M. A. Osinova
    • 1
  • A. N. Nesmeyanov
    • 1
  1. 1.Institute of Heteroorganic Compounds of the Academy of Sciences of the USSRUSSR

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