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Stereochemistry of cyclic compounds Communication 56. Steric orientation in the diene condensation of 1-(1-chlorovinyl)cyclohexene with trans-1-nitropropene

  • Organic and Biological Chemistry
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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Summary

  1. 1.

    A study was made of structural and spatial orientation in the diene condensation of 1-(1-chlorovinyl)cyclohexene (IV) with trans-1-nitropropene, and the configurations of the adduct (V) and its isomer (VII) were proved.

  2. 2.

    The laws underlying the transformations and stereochemistry of the products formed in the acid hydrolysis and reduction of the isomeric chloronitrooctalins (V) and (VII) were elucidated.

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Literature cited

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Authors and Affiliations

  1. N. D. Zelinskii Institute of Organic Chemistry, Academy of Sciences, USSR

    G. M. Segal', L. P. Rybkina & V. F. Kucherov

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  1. G. M. Segal'
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  2. L. P. Rybkina
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  3. V. F. Kucherov
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Segal', G.M., Rybkina, L.P. & Kucherov, V.F. Stereochemistry of cyclic compounds Communication 56. Steric orientation in the diene condensation of 1-(1-chlorovinyl)cyclohexene with trans-1-nitropropene. Russ Chem Bull 12, 1293–1298 (1963). https://doi.org/10.1007/BF00847799

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  • DOI: https://doi.org/10.1007/BF00847799

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