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Catalytic reduction of aromatic nitroso compounds with 2,6-dimethyl-3, 5-diethoxycarbonyl-1, 4-dihydropyridine

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Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The reduction of aromatic nitroso compounds with 2,6-dimethyl-3,5-diethoxycarbonyl-1,4-dihydropyridine is catalyzed by flavins, quinones, and related substances.

  2. 2.

    The rate of the non-catalytic reactions depends markedly on the nature of the substituents in the para position to the nitroso group and increases in the sequence: N(CH3)2 < OCH3 < H < COOC2H5 < NO2. The rate of the catalytic reactions increases in the same sequence, but depends on the substituent to a smaller degree.

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Authors and Affiliations

  1. Institute of Chemical Physics, Academy of Sciences of the USSR, USSR

    D. D. Mozzhukhin & M. L. Khidekel'

Authors
  1. D. D. Mozzhukhin
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  2. M. L. Khidekel'
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Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1263–1265, July, 1966.

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Mozzhukhin, D.D., Khidekel', M.L. Catalytic reduction of aromatic nitroso compounds with 2,6-dimethyl-3, 5-diethoxycarbonyl-1, 4-dihydropyridine. Russ Chem Bull 15, 1216–1218 (1966). https://doi.org/10.1007/BF00847770

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  • DOI: https://doi.org/10.1007/BF00847770

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