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Polymerization of 2-chloroacrolein

  • Organic and Biological Chemistry
  • Published:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science Aims and scope

Conclusions

  1. 1.

    The polymerization of 2-chloroacrolein was carried out for the first time by ionic and radical mechanisms. The properties of the polymers obtained were studied.

  2. 2.

    The radical polymerization of 2-chloroacrolein in the presence of a redox system goes at carbon-carbon bonds with formation of a poly-2-chloroacrolein with a molecular weight of greater than 70,000. In polymerization by an ionic mechanism in the presence of stannous chloride and by a radical mechanism in the presence of hydrogen peroxide 2-chloroacrolein polymers of low molecular weight (oligomers) were formed.

  3. 3.

    In the UV irradiation of the polymer in the presence of a sensitizer (butanone), a change in some of its properties is observed.

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Authors and Affiliations

  1. Irkutsk Institute of Organic Chemistry, Siberian Division of the Academy of Sciences of the USSR, USSR

    V. I. Belyaev, V. Z. Annenkova, G. S. Ugryumova & L. T. Ivanova

Authors
  1. V. I. Belyaev
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  2. V. Z. Annenkova
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  3. G. S. Ugryumova
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  4. L. T. Ivanova
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Additional information

Translated from Izvestiya Akademii Nauk SSSR, Seriya Khimicheskaya, No. 7, pp. 1251–1254, July, 1966.

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Belyaev, V.I., Annenkova, V.Z., Ugryumova, G.S. et al. Polymerization of 2-chloroacrolein. Russ Chem Bull 15, 1202–1204 (1966). https://doi.org/10.1007/BF00847764

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  • DOI: https://doi.org/10.1007/BF00847764

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