Summary
-
1.
Oxidation of phenols by lead tetraacetate takes place with intermediate formation of phenoxyl radicals.
-
2.
The spectra of radicals formed by oxidation of phenol and a number of para-alkyl phenols by lead tetraacetate were investigated for the first time.
Literature cited
N. M. Emanuel' and Yu. N. Lyaskovskaya, Inhibition of Oxidation Processes of Fats [in Russian], Moscow (1961).
N. M. Emanuel', Report to the Fifth MBK, Symposium 4 [in Russian], Moscow (1961).
J. Becconssel, S. Clough, and G. Scott, Trans. Faraday Soc.56, 459 (1959).
A. L. Buchachenko, Ya. S. Lebedev, and M. B. Neiman, Zh. strukt, khimii2, 5, 558 (1961).
J. Bennet, Nature186, 385 (1960).
F. Muller, R. Mayer, H. Heilmann, and K. Scheffler, Ann.645, 66 (1961).
G. N. Bogdanov and V. V. Ershov. Izv. AN SSSR, Otd. khim. n.1962, 2145.
F. Wesseli and F. Sinwel, Monatsh.81, 1055 (1950).
A. G. Semenov, and N. N. Bubnov, Pribory i tekhnika eksperimenta1, 91 (1959).
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Bogdanov, G.N., Postnikova, M.S. & Emanuel', N.M. The formation of phenoxyl radicals by oxidation of phenols by lead tetraacetate. Russ Chem Bull 12, 154–156 (1963). https://doi.org/10.1007/BF00846968
Received:
Issue Date:
DOI: https://doi.org/10.1007/BF00846968